Characterization of Biochar Empty Fruit Bunches OPEFB at Various Temperatures and Burning Time
DOI:
https://doi.org/10.18006/2022.10(3).599.606Keywords:
Biochar, OPEFB, Nutrient, FTIR, BiowasteAbstract
Oil palm waste (OPW), comprising mainly of empty fruit bunch, mesocarp fiber, frond, trunk, and palm kernel shell generated from the palm oil industry, was collected, characterized, and then pyrolyzed to evaluate their potential to be converted into biochar. Oil Palm Empty Fruit Bunches (OPEFB) are a source of organic material with abundant nutrients and are highly potentially useful as biochar. This article provides experimental data for the production of biochar at a temperature range of 100 to 300 °C at time of 4 to 8 hours. The chemical components examined are pH, CEC, C-Organic, N-total, C/N, K dd, P, Ca, Mg, and Na, using Fourier Transform Infrared Spectroscopy (FTIR). The results showed that organic C, nitrogen, and pH were highest at 200–300 °C and had a burning time of 8 hours. Furthermore, the highest concentrations of P, Ca, and Mg were recorded at 200–300°C after 5 hours, Kdd at 100–200 °C after 5 hours, and Na and CEC at 200–300 °C after 4 hours. The transmittance intensity produced by the spectrum of hydroxyl (O-H) vibrations, carbonyl stretching (C=O), alkanes (-CH), and aromatics (C=C) decreased with increasing time, while stretching alcohol (C-O) vibrations increased with time. Our results demonstrate that OPEB is a biowaste that shows exceptional promise to be transformed into high-grade biochar rather than simply disposed of by landfilling or burning.
References
Bi, H., Ni, Z., Tian, J., Wang, C., et al. (2021). The effect of biomass addition on pyrolysis characteristics and gas emission of coal gangue by multi-component reaction model and TG-FTIR-MS. The Science of the total environment, 798, 149290. https://doi.org/10.1016/j.scitotenv.2021.149290. DOI: https://doi.org/10.1016/j.scitotenv.2021.149290
Dominguez, E.L., Uttran, A., Loh, S.K., Manero, M.H., et al. (2020). Characterisation of Industrially Produced Oil Palm Kernel Shell Biochar and Its Potential as Slow Release Nitrogen-Phosphate Fertilizer and Carbon Sink. Materials Today: Proceedings, 31(1), 221–27. DOI: https://doi.org/10.1016/j.matpr.2020.05.143
Ferreiraa, M.F.P., Oliveira, B.F.H., Pinheiro, W.B.S., Correa, N.F., França, L.F., Ribeiro, N.F.P. (2020). Generation of Biofuels by Slow Pyrolysis of Palm Empty Fruit Bunches: Optimization of Process Variables and Characterization of Physical-Chemical Products. Biomass and Bioenergy 140: 105707. https://doi.org/10.1016/j.biombioe.2020.105707. DOI: https://doi.org/10.1016/j.biombioe.2020.105707
Ghorbani, M., Asadi, H., Abrishamkesh, S. (2019). Effects of Rice Husk Biochar on Selected Soil Properties and Nitrate Leaching in Loamy Sand and Clay Soil. International Soil and Water Conservation Research, 7(3), 258–265. https://doi.org/10.1016/ j.iswcr.2019.05.005. DOI: https://doi.org/10.1016/j.iswcr.2019.05.005
Gupta, G.K., Ram, M., Bala, R., Kapur, M., & Mondal, M.K. (2018). Pyrolysis of chemically treated corncob for biochar production and its application in Cr(VI) removal. Environmental Progress and Sustainable Energy, 37, 1606-1617. https://doi.org/ 10.1002/ep.12838. DOI: https://doi.org/10.1002/ep.12838
Ighalo, J.O., Adeniyi, A.G., Eletta, O.A.A., & Arowoyele, L.T. (2021) Competitive adsorption of Pb(II), Cu(II), Fe(II) and Zn(II) from aqueous media using biochar from oil palm (Elaeis guineensis) fibers: a kinetic and equilibrium study. Indian Chemical Engineer, 63 (5), 501-511. DOI: 10.1080/00194506.2020.1787870 DOI: https://doi.org/10.1080/00194506.2020.1787870
Mukherjee, A., & Zimmerman, A.R. (2013). Organic Carbon and Nutrient Release from a Range of Laboratory-Produced Biochars and Biochar-Soil Mixtures. Geoderma, 193–194, 122–30. DOI: https://doi.org/10.1016/j.geoderma.2012.10.002
Pierzynski, G.M. (2009) Methods of Phosphorus Analysis for Soils, Sediments , Residuals , and Waters. In Kovar, J.L. (ed) USDA-ARS National Soil Tilth Laboratory 2110 University Blvd. Ames, IA 50011-3120 GaryJune: Virginia Tech University. Retrieved from http://www.sera17.ext.vt.edu/Documents/ P_Methods2ndEdition2009.pdf%0AContact.
Qiao, Y., Wang, B., Zong, P., Tian, Y., et al. (2019) Thermal Behavior, Kinetics and Fast Pyrolysis Characteristics of Palm Oil: Analytical TG-FTIR and Py-GC/MS Study. Energy Conversion and Management, 199, 111964. https://doi.org/10.1016/ j.enconman.2019.111964. DOI: https://doi.org/10.1016/j.enconman.2019.111964
Razali, N., & Kamarulzaman, N.Z. (2020). Chemical Characterizations of Biochar from Palm Oil Trunk for Palm Oil Mill Effluent (POME) Treatment.” Materials Today: Proceedings 31(1): 191–97. https://doi.org/10.1016/j.matpr.2020.02.219. DOI: https://doi.org/10.1016/j.matpr.2020.02.219
Rosli, N. S., Harun S., Jahim J. Md., & Othaman, R. (2016). Chemical and physical characterization of oil palm empty fruit bunch. Malaysian Journal of Analytical Sciences, 21(1), 188 - 196. DOI: https://doi.org/10.17576/mjas-2017-2101-22
Selvarajoo, A., & Oochit, D. (2020). Effect of Pyrolysis Temperature on Product Yields of Palm Fibre and Its Biochar Characteristics. Materials Science for Energy Technologies 3: 575–83. https://doi.org/10.1016/j.mset.2020.06.003. DOI: https://doi.org/10.1016/j.mset.2020.06.003
Spokas, K. A., Cantrell, K. B., Novak, J. M., Archer, D. W., et al. (2012). Biochar: a synthesis of its agronomic impact beyond carbon sequestration. Journal of environmental quality, 41(4), 973–989. https://doi.org/10.2134/jeq2011.0069. DOI: https://doi.org/10.2134/jeq2011.0069
Shaaban, M., Van Zwieten, L., Bashir, S., Younas, A., et al. (2018). A concise review of biochar application to agricultural soils to improve soil conditions and fight pollution. Journal of environmental management, 228, 429–440. https://doi.org/ 10.1016/j.jenvman.2018.09.006. DOI: https://doi.org/10.1016/j.jenvman.2018.09.006
Sukmawati, Ala, A., Patandjengi, B., & Gusli, S. (2020). The Physicochemical Properties of Agricultural Waste Inoculated with Alginate-Producing Bacteria: Structural Modification For Biochar Stability As A Soil Amendment Formula. Plant Cell Biotechnology and Molecular Biology, 21, 87–101.
Sung, C.T.B. (2016) Availability , Use , and Removal of Oil Palm Biomass in Indonesia. Working Paper Retrieved From
https://theicct.org/sites/default/files/publications/Teh_palm%20residues_final.pdf
Tippayawong, N., Rerkkriangkrai, P., Aggarangsi, P., & Pattiya, A., (2018) Characterization of Biochar from Pyrolysis of Corn Residues in a Semi-continuous Carbonizer. Chemical Engineering Transactions, 70, 1387-1392.
Zhang, H., Chen, C., Gray, E.M. & Boyd, S.E. (2017) Effect of Feedstock and Pyrolysis Temperature on Properties of Biochar Governing End Use Efficacy. Biomass and Bioenergy, 105, 136–46. http://dx.doi.org/10.1016/j.biombioe.2017.06.024. DOI: https://doi.org/10.1016/j.biombioe.2017.06.024
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